The maximum output power density (Pout) in GaN RF power devices at X-band has remained around 30–33 W/mm for nearly two decades, mainly constrained by the device’s high thermal resistance (RT). This work demonstrates a new record Pout of 41 W/mm at 10 GHz in an AlGaN/GaN/AlN-on-SiC RF power HEMT. This breakthrough is enabled by deploying an ultra-wide-bandgap (UWBG) AlN buffer and reducing the combined channel and buffer thickness to just 400 nm. By optimizing the V:III ratio and growth rate during AlN epitaxy, we suppress conventional island-like nucleation, achieving rapid film coalescence, low dislocation density, and reduced thickness. Thermoreflectance (TR) measurements reveal a low device RT of 2.1 K•mm/W, which is less than one-third of conventional devices with μm-thick GaN buffer and island-nucleated AlN layer. Meanwhile, the use of UWBG AlN buffer and thin GaN channel boost …